期刊
TETRAHEDRON
卷 64, 期 49, 页码 11335-11348出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.08.084
关键词
Enantioselective allylation; Allylsilane; Organocatalysis; Asymmetric catalysis; Pyridine N-oxides
资金
- Schering-Plough (formerly Organon)
- Ministry of Education and Science of Spain
- Socrates-Erasmus exchange program
- Czech Science Foundation [203/08/0350]
- Ministry of Education of the Czech Republic [LC06070, MSM0021620857, MSM6046137301]
- University of Glasgow
- Engineering and Physical Sciences Research Council [GR/T27051/01] Funding Source: researchfish
Asymmetric allylation of aromatic aldehydes 1 with allyltrichlorosilane (2) can be catalyzed by new terpene-derived bipyridine N,N'-dioxides 12-15 and an axially chiral biisoquinoline dioxide 17b with good enantioselectivities. Dioxides have been found to be more reactive catalysts than their monooxide counterparts. Crown Copyright (C) 2008 Published by Elsevier Ltd. All rights reserved.
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