期刊
TETRAHEDRON
卷 64, 期 21, 页码 4736-4757出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.02.108
关键词
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资金
- NCI NIH HHS [R01 CA100101, R01 CA100101-02, R01 CA100101-01A3, R01 CA100101-03] Funding Source: Medline
A concise and efficient cascade-based total synthesis of artochamins F, H, I, and J is described. The potential biogenetic connection between artochamin F, or a derivative thereof, and artochamins H, I, and J, through an unusual formal [2+2] cycloaddition process, was shown to be feasible. An alternative mechanism for this transformation is also proposed. (C) 2008 Elsevier Ltd. All rights reserved.
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