期刊
TETRAHEDRON
卷 64, 期 50, 页码 11469-11474出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.08.059
关键词
Alkyne; Annulene; Carbon-rich; Fluorophore; Chromophore
Titration of three electron donor-functionalized bis(dehydrobenzo[n]annuleno)benzenes and a corresponding acyclic 1,2,4,5-tetrakis(phenylethynyl)benzene derivative with trifluoroacetic acid in CH2Cl2 resulted in two-stage emission switching behavior in which initial acidification caused bathochromic shifts, followed by dramatic hyposchromic Shifts upon further addition of acid. Differences in the various spectra are rationalized by structure and chromophore architecture. The results indicate independent manipulation of frontier molecular orbital energy levels by stepwise ion addition, therefore Suggesting transient and tunable intramolecular charge transfer systems upon partial protonation. (C) 2008 Elsevier Ltd. All rights reserved.
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