Conducting polymer coated single-walled carbon nanotube gas sensors for the detection of volatile organic compounds

The current work involves fabrication, characterization and subsequent evaluation of poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonic acid) (PEDOT:PSS) coated single walled carbon nanotubes (SWNTs) sensors for detecting analytes of interest in industrial manufacturing. By varying the conducting polymer's synthesis conditions in terms of charge controlled electropolymerization of the monomer EDOT in presence of the dopant PSS, the sensing performance of the PEDOT:PSS functionalized SWNT sensors was systematically optimized. Electrical characterization in terms of change in resistance, cyclic voltammetry and field-effect transistor measurements was performed to confirm the presence of PEDOT:PSS coating on SWNTs. The optimized sensors exhibited sensing properties over a wide dynamic range of concentrations towards saturated vapors of volatile organic compounds (VOCs) such as methanol, ethanol and methyl ethyl ketone (MEK) at room temperature. The limit of detection of this sensor was found to be 1.3%, 5.95% and 3% for saturated vapors of methanol, ethanol and methyl ethyl ketone (MEK) respectively. In terms of performance, when compared with bare SWNTs, these hybrid sensors exhibited better sensitivity. The underlying mechanism of sensing was also investigated by using them in chemFET mode of sensor configuration. (C) 2014 Elsevier B.V. All rights reserved.