期刊
TALANTA
卷 99, 期 -, 页码 213-224出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.talanta.2012.05.042
关键词
Phenolic compounds; Flavonoids; Mass spectrometry; Structural characterization; HPLC; Citrus; Juices
资金
- Gobierno Vasco [IT413-10]
- Ministerio de Ciencia e Innovacion [CTQ2009-08390]
- Universidad del Pais Vasco/Euskal Herriko Unibertsitatea
- Gobierno Vasco/ Eusko Jaurlaritza
Polyphenol profile of Citrus juices of sweet orange, tangerine, lemon and grapefruit from Spanish cultivars was obtained by High-Performance Liquid Chromatography with Diode Array Detection coupled to Electrospray ionization and Triple Quadrupole Mass Spectrometry. Fifty eight phenolic compounds of five different classes were identified in these Citrus juices. Flavanone: O-dihexoside of naringenin; flavones: apigenin-7-O-rutinoside-4'-O-glucoside, luteolin-7-O-neohesperidoside-4'-O-glucoside, luteolin-6-C-glucoside, 6,8-di-C-acylhexosides of chrysoeriol and diosmetin, 6C- and -8C-glucoside-O-pentoside of apigenin, apigenin-6-C-hexoside-O-hexoside and apigenin-8-C-hexoside-O-acylrhamnoside; flavonols: 7-O-rutinosides of quercetin, kaempferol, isorhamnetin and tamarixetin, kaempferol-3-O-rutinoside, isorhamnetin-3-O-rutinoside-7-O-glucoside, tamarixetin-3-O-rutinoside-7-O-glucoside, isorhamnetin-3-O-hexoside-7-O-rhamnosylhexoside, 3-O-rhamnoside-7-O-rhamnosylhexoside of quercetin and isorhamnetin and kaempferol-3-O-rhamnosylhexoside-7-O-rhamnoside; hydroxycinnamic acids: O-hexoside of ferulic and sinapic acid; and, coumarins: O-hexoside and O-rhamnosylhexoside of scopoletin, had not previously been reported in Citrus juices to our knowledge. Structures have been assigned on the basis of the complementary information obtained from retention time, UV-visible spectra, scan mode MS spectra, and fragmentation patterns in MS2 spectra obtained using different collision energies. A structure diagnosis scheme is provided for the identification of different phenolic compounds. (C) 2012 Elsevier B.V. All rights reserved.
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