Highly sensitive and selective colorimetric detection of cartap residue in agricultural products

The residue of pesticide has posed a serious threat to human health. Fast, broad-spectrum detection methods are necessary for on-site screening of various types of pesticides. With citrate-coated Au nanoparticles (Au NPs) as colorimetric probes, a visual and spectrophotometric method for rapid assay of cartap, which is one of the most important pesticides in agriculture, is reported for the first time. Based on the color change of Au colloid solution from wine-red to blue resulting from the aggregation of Au NPs, cat-tap could be detected in the concentration range of 0.05-0.6 mg/kg with a low detection limit of 0.04 mg/kg, which is much lower than the strictest cat-tap safety requirement of 0.1 mg/kg. Due to the limited research on the rapid detection of cat-tap based on Au NPs, the performance of the present method was evaluated through aggregation kinetics, interference influence, and sample pretreatment. To further demonstrate the selectivity and applicability of the method, cartap detection is realized in cabbage and tea with excellent analyte concentration recovery. These results demonstrate that the present method provides an easy and effective way to analyze pesticide residue in common products, which is of benefit for the rapid risk evaluation and on-site screening of pesticide residue. (C) 2012 Elsevier B.V. All rights reserved.