期刊
TALANTA
卷 84, 期 4, 页码 1124-1132出版社
ELSEVIER
DOI: 10.1016/j.talanta.2011.03.015
关键词
Imidazole; Molecularly imprinted polymer; Synthesis; Solid phase extraction
资金
- National Natural Science Foundation of China [20977025]
- Doctoral Foundation of Ministry of Education of China [200804760004]
A surface molecularly imprinted polymer (MIP) was synthesized by using imidazole as the template and modified silica particles as the support material. The static adsorption, solid phase extraction (SPE) and high-performance liquid chromatography (HPLC) experiments were performed to investigate the adsorption properties and selective recognition characteristics of the polymer for imidazole and its structural analogs. It was shown that the maximum binding capacities of imidazole on the MIP and the non-imprinted polymer (NIP) were 312 and 169 mu mol g(-1), respectively. The adsorption was fast and the adsorption equilibrium was achieved in 30 min. The binding process could be described by pseudo-second order kinetics. Compared with the corresponding non-imprinted polymer, the molecularly imprinted polymer exhibited much higher adsorption performance and selectivity for imidazole. The selective separation of imidazole from a mixture of 1-hexyl-3-methylimidazolium bromide ([C-6 mim][Br]) and 2,4-dichlorophenol could be achieved on the MIP-SPE column. The recoveries of imidazole and [C-6 mim][Br] were 97.6-102.7% and 12.2-17.3%, respectively, but 2,4-dichlorophenol could not be retained on the column. The surface molecularly imprinted polymer presented here may find useful application as a solid phase absorbent to separate trace imidazole in environmental water samples. This may also form the basis for our research program on the preparation and application of alkyl-imidazolium imprinted polymers. (C) 2011 Elsevier B.V. All rights reserved.
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