Novel fluorimetric bulk optode membrane based on 5,8-bis((5′-chloro-8′-hydroxy-7′-quinolinyl)methyl)-2,11-dithia-5,8-diaza-2,6-pyridinophane for selective detection of lead(II) ions

A novel fluorescence chemical sensor for the highly sensitive and selective determination of Pb2+ ions in aqueous solutions is described. The preliminary potentiometric and spectrofluorimetric complexation studies in solution revealed that the lipophilic ligand 5',8-bis((5'-chloro-8'-hydroxy-7'-quinolinyl)methyl)-2,11-dithia-5,8-diaza-2,6-pyridinophane (L2) forms a highly stable and selective [PbL2](2+) and [Pb(L2)(2)](2+) complexes which results in a strong fluorescence quenching of the ligand. Thus, a novel fluorescence Pb2+ sensing system was prepared by incorporating L2 as a neutral lead-selective fluoroionophore in the plasticized PVC membrane containing tetrakis(p-chlorophenyl) borate as a liphophilic anionic additive. The response of the sensor is based on the strong selective fluorescence quenching of L2 by Pb2+ ions At pH 5.5. the proposed sensor displays a calibration curve over a wide concentration range of 3.0 x 10(-7) to 2.5 x 10(-2) M with a relatively fast response time of less than 5 min. In addition to high stability, reversibility and reproducibility, the sensor shows a unique selectivity towards Pb2+ ion with respect to common coexisting cations. The proposed fluorescence optode was successfully applied to the determination of lead in plastic toys and tap water samples. (C) 2009 Elsevier B.V All rights reserved.