期刊
TALANTA
卷 82, 期 3, 页码 939-944出版社
ELSEVIER
DOI: 10.1016/j.talanta.2010.05.062
关键词
Copper; Water samples; Polypyrrole-chloride; Pyrocatechol violet; Solid phase; Extraction
资金
- Scientific Research Projects (SRP) Coordination Unit of Pamukkale University [2009FBE014]
Polypyrrole-chloride was studied as a new sorbent for preconcentration of copper(II) using solid-phase extraction prior to determination by flame atomic absorption spectrometry. The sorbent showed an extremely high selectivity towards copper(II) as an anionic chelate, i.e. Cu (pyrocatechol violet)2(2-) in the pH range of 4-7. Copper(II) as Cu (pyrocatechol violet)2(2-) was selectively retained on a column containing 1.0 g of polypyrrole-chloride and quantitatively eluted by 3 mL of 2.0 mol L-1 nitric acid. The calibration graph was linear with a correlation coefficient of 0.999 at levels near the detection limit and up to at least 50 mu g L-1. When applied for preconcentration and determination of copper in tap water, waste water and hot spring water, the recoveries were found to be 96, 101 and 95%, respectively, with high precision (% relative standard deviation <4%) and low detection limit (0.87 mu g L-1). Verification of the accuracy was carried out by the analysis of a standard reference material (BCR 715 wastewater-SRM). The relative error was +3.33%. The proposed method was successfully applied to the determination of copper in tap water, waste water and hot spring water samples. (C) 2010 Elsevier B.V. All rights reserved.
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