期刊
TALANTA
卷 77, 期 1, 页码 60-65出版社
ELSEVIER
DOI: 10.1016/j.talanta.2008.05.050
关键词
Analytical validation; Quantification; Trace elements; Natural colloids; FFF; ICP-MS
A quantification procedure of trace elements during colloid size fractionation was developed and validated. This procedure is based on the hyphenation between Asymmetrical Flow Field-Flow Fractionation (As-Fl-FFF) and Inductively Coupled Plasma Mass Spectrometer (ICP-MS). The optimisation of the procedure was performed on a soil leachate spiked with six trace elements selected for their environmental and health impact (As, Cd, Sb, Se, Sn and Pb). The elements in the spiked sample were on-line monitored during the fractionation. The validation was carried out by comparison with a second off-line quantification procedure based on fraction collection and total element analysis by ICP-MS. This off-line one was previously validated using reference materials. Finally, the analytical performances of the two procedures were compared. (C) 2008 Elsevier B.V. All rights reserved.
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