Organic single crystalline micro- and nanowires field-effect transistors of a tetrathiafulvalene (TTF) derivative with strong pi-pi orbits and S center dot center dot center dot S interactions

Tetrathiafulvalene (TTF) was one of the most widely studied heterocyclic systems. However, TTF itself was easily oxidized, which induced the low stability and limited its potential applications. Here, a TTF derivative, 2,3,6,7-tetrakis(2-cyanoethylthio)tetrathiafulvalene (TCE-TTF), was synthesized. It was found that single crystalline micro- and nanowires of TCE-TTF were easily obtained by simple casting due to the enhanced pi-pi overlapping and S center dot center dot center dot S interaction. The thermal and vacuum stability analyses revealed TCE-TTF was much better than TTF. Single crystalline micro- and nanowires field-effect transistors were also fabricated by in situ dropping method. The typical mobility and on/off ratio were similar to 0.02 cm(2)/V s and similar to 10(3), which predicted great potential applications of organic nanowires electronics. (C) 2010 Elsevier B.V. All rights reserved.