期刊
SYNTHETIC METALS
卷 160, 期 5-6, 页码 413-418出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.synthmet.2009.11.021
关键词
Conducting polymer; Electrochemical polymerization; Electrochromism; Spectroelectrochemistry; Poly-(2,5-di(2-thienyl)-1H-pyrrole) derivative
资金
- Pusan National University
Poly(ter-heteroaromatic(thiophene-pyrrole-thiophene)), PDPB, was electrochemically prepared from the 2,5-di(2-thienyl)-1H-pyrrole-1-(p-benzoic acid) (DPB) monomer using the Paal-Knorr pyrrole condensation reaction. The structure of the monomer was confirmed using H-1-, C-13 NMR, FT-IR and mass spectroscopy. The maximum UV-visible absorption and PL emission bands of DPB were observed at 330 nm and 500 nm, respectively. The cyclic voltammograms (CVs) recorded for the electrochemically polymerized DPB revealed a set of redox peaks at 0.65/0.53 V. The conductivity monotonically increased with respect to the applied potential from 0.0 V to 1.0 V, exhibiting a maximum conductivity of 0.18 S/cm at +0.80 V. The in situ UV-visible spectroelectrochemical analysis of PDPB revealed electronic transitions at 420 nm, 654 nm, and 870 nm corresponding to the pi-pi* transition, polaron, and bipolaron states, respectively. The optical band-gap (E-g) of PDPB was 2.16 eV. The color of the PDPB film transitioned yellow (at 0.0 V) to blue (at 1.0 V) when the potential was switched between the reduced and oxidized states with a good electrochromic response time (0.95 s). (C) 2009 Elsevier B.V. All rights reserved.
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