期刊
SYNTHETIC METALS
卷 159, 期 15-16, 页码 1583-1588出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.synthmet.2009.04.020
关键词
Conducting polymers; Polyaniline; Benzoyl peroxide; Plate; Microstructure
资金
- National Natural Science Foundation of China [20676095, 20836006]
- New Century Excellent Talents in University and Advanced Materials Ltd., Co. (Tianjin)
Two-dimensional plate-like PANI are successfully synthesized by a self-assembly process using benzoyl peroxide as oxidant. The micelles formed by aniline/p-TSA salt serves as 'soft template' to form PANI micro/nanostructures and proper [An]/[acid] ratios are required for the formation of plate-like PANI. It is found that at high [An]/[p-TSA] ratios (5:1 to 2:1) plate-like PANI are obtained, while at low [An]/[p-TSA] ratios ranging from 1:1 to 1:3 PANI nanoparticles are obtained. The influence of the other synthetic parameters, such as temperature, the concentration of benzoyl peroxide and stirring, on the morphologies of the PANI micro/nanostructures has also been investigated. Fourier transform infrared (FTIR), UV-vis spectroscopy (UV-vis), X-ray photoelectron spectroscopy (XPS), as well as X-ray diffraction (XRD) and cyclic voltammeter method (CV) are applied to characterize the products. (C) 2009 Elsevier B.V. All rights reserved.
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