期刊
SYNTHETIC COMMUNICATIONS
卷 41, 期 19, 页码 2946-2951出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2010.515432
关键词
Aromatic nitration; nitric acid; regioselective; transition-metal complexes
Aromatic compounds were efficiently nitrated under facile reaction conditions by employing 69% nitric acid catalyzed by transition-metal complexes such as [Co(NH3)(5)Cl]Cl-2, [Cu(NH3)(4)]SO4, Mn(acac)(3), [Ni(NH3)(6)]Cl-2, [Ni(en)(3)]S2O3, and Hg[Co(SCN)(4)]. The reaction was completed smoothly at room temperature and afforded corresponding mono-nitro derivatives in quantitative yield. This new method offers efficient and facile regioselective mononitration of aromatic compounds.
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