期刊
SYNTHETIC COMMUNICATIONS
卷 40, 期 23, 页码 3438-3446出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/00397910903434562
关键词
Benzoisoselenazolone; organoselenium-saccharide derivatives; reaction mechanism
资金
- Chinese Ministry of Science and Technology [2008DFA31040]
A new class of organoselenium-saccharide derivatives, 2-amino-2-deoxy--D-glucose-modified benzo[d][1,2]selenazol-3-(2H)-one derivatives, has been synthesized via the cyclization reaction of 2-(chloroseleno)benzoyl chloride and O-protected D-glucosamine derivatives. An efficient synthetic method for the preparation of this type of compounds was developed. It has been found that acetone can react with the chloroseleno group under basic conditions, and organoselenium-saccharide derivatives with free hydroxy groups were obtained only when the OH-1 group of the saccharide was protected.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据