期刊
SYNTHETIC COMMUNICATIONS
卷 38, 期 12, 页码 1958-1971出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/00397910801997710
关键词
beta'-acetamido-beta-dicarbonyls; Lewis acid; one-pot multicomponent synthesis; ZrOCl2 center dot 8H(2)O
ZrOCl2 center dot 8H(2)O catalyzes the one-pot synthesis of beta'-acetamido-beta-dicarbonyl compounds in high yields from aldehyde, enolizable beta-dicarbonyl compound, acetyl chloride, and acetonitrile in solvent as well as in solvent-free conditions. beta'-Acetamido-beta-ketoesters are formed in moderate to exclusive pref-diastereoselectivity.
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