期刊
SYNTHESIS-STUTTGART
卷 50, 期 19, 页码 3843-3861出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1609583
关键词
alkenes; copper catalysis; hydroboration; asymmetric; mechanism; 1,3-diols; total synthesis
The efficient synthesis of enantioenriched organoboron compounds has been recognized as an important topic in recent years. As an update review, this article aims to select key achievements in copper-catalyzed, electron-deficient alkene enantioselective hydroboration methodologies since the beginning of 2017. In addition, it covers relevant mechanistic investigations developed over the last six years, as well as total synthesis applications for preparing 1,3-diols as important medicinal intermediates.
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