期刊
SYNTHESIS-STUTTGART
卷 47, 期 1, 页码 22-33出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1378918
关键词
cycloaddtion; oxyallyl cation; heterocycles; regioselectivity; diastereoselectivity
资金
- NIH-NIGMS [1R01GM111638-01]
- Dartmouth College
The (3+2)-cycloaddition reaction involving oxyallyl cations has proven to be a versatile and efficient approach for the construction of five-membered carbo-and heterocycles, which are prevalent frameworks in natural products and pharmaceuticals. The following article will provide a brief summary of recent disclosures on this process featuring chemo-, regio- and diastereoselective oxyallyl cycloadditions with both electron-rich and electron-deficient 2 pi partners.
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