期刊
SYNTHESIS-STUTTGART
卷 46, 期 22, 页码 2983-3003出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1379255
关键词
amination; asymmetric catalysis; tetrasubstituted carbon; stereogenic center; Lewis acid catalysis; organocatalysis
资金
- NSFC [21172075, 21222204]
- Ministry of Education [NCET-11-0147]
- Ministry of Education (PCSIRT)
- SSCS [13XD1401600]
The catalytic asymmetric electrophilic amination has been established as a fruitful methodology for the construction of nitrogen-bearing tetrasubstituted carbon stereocenters, with its roots nourished by the latest achievements in chiral catalysis and synthetic strategies. This review summarizes the recent progresses, briefly discusses the reaction mechanism and challenges in this context, and outlines synthetic opportunities for future development. 1Introduction 2Transformations Based on Azodicarboxylates 2.1-Substituted Prochiral Aldehydes and Ketones 2.2Ketenes 2.3Doubly Activated Dicarbonyl Compounds 2.4Heteroatom-Containing Activated Methines 2.5Heterocyclic Nucleophiles 3Amination Reactions Using other Amination Reagents 4Conclusion
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