期刊
SYNTHESIS-STUTTGART
卷 46, 期 6, 页码 817-821出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1338584
关键词
natural products; pyrenolide D; oxycarbonylation; palladium catalysis; iron pentacarbonyl
资金
- Slovak Grant Agency (APVV, Bratislava) [APVV-0203-10]
- Slovak Grant Agency (ASFEU, Bratislava, ITMS) [26240120001, 26240120025]
A concise, asymmetric formal synthesis of (+)-pyrenolide D from (E)-crotonaldehyde is described. The key steps include an enantioselective Sharpless dihydroxylation of protected hex-4-en-1-yn-3-ol and a highly diastereoselective palladium-catalysed oxycarbonylation of (2R,3S,4S)-hex-5-ene-2,3,4-triol using iron pentacarbonyl as the carbon monoxide source.
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