期刊
SYNTHESIS-STUTTGART
卷 46, 期 18, 页码 2471-2480出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1378280
关键词
active methylene compounds; cross-metathesis; Diels-Alder reaction; enyne metathesis; spirocyclic compounds
资金
- DST-New Delhi
- University Grants Commission, New Delhi
- Department of Science and Technology
We have developed a simple and an efficient route to a range of angularly fused spirocycles by the application of enyne metathesis and the Diels-Alder reaction as key steps. The enyne metathesis protocol has been further extended to the dibenzylation of indane-1,3-dione by using cross-enyne metathesis in the presence of hexa-1,5-diene with the aid of Grubbs' 1st generation catalyst followed by an aromatization sequence with DDQ.
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