期刊
SYNTHESIS-STUTTGART
卷 47, 期 1, 页码 134-140出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1379043
关键词
palladium; allylic substitution; asymmetric catalysis; indolines; quaternary carbon
资金
- Major Basic Research Development Program [G 2010CB833300]
- National Natural Science Foundation of China [21121062, 21032007, 21302205]
- Chinese Academy of Sciences
- Technology Commission of Shanghai Municipality
- Croucher Foundation of Hong Kong
An efficient and practical method was developed for the synthesis of 2,2-disubstituted indolin-3-ones by palladium-catalyzed asymmetric allylic alkylation. Enantioselective construction of quaternary carbon centers was also realized in this way.
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