期刊
SYNTHESIS-STUTTGART
卷 45, 期 3, 页码 281-307出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1316840
关键词
catalysis; cross-coupling; reduction; stereoselectivity; umpolung
资金
- Fonds der Chemischen Industrie
- Deutsche Forschungsgemeinschaft (DFG) [STR 1150/3-1]
Reductive umpolung reactions of saturated and unsaturated carbonyl compounds enable the direct synthesis of 1,2-, 1,4-, 1,6-, etc. substituted carbon frameworks that are difficult to access by other methodologies. Herein, the evolution from stoichiometric to catalytic processes with high chemo-, regio- and stereoselectivity is discussed for each carbon-carbon bond connection type. At certain points, summaries of the known reaction conditions and discussions of the underlying mechanisms are included.
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