期刊
SYNTHESIS-STUTTGART
卷 45, 期 11, 页码 1529-1533出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1338423
关键词
manganese(III) acetate; phosphonylation; pyridinone; pyrimidinone; dialkyl phosphite; free radical
资金
- National Natural Science Foundation of China [20772088, 21172163]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
The phosphonyl radical generated from the reaction of dimethyl phosphite with manganese(III) acetate adds selectively to the 3-position of pyridin-2-ones or the 5-position of pyrimidin-4-ones to afford phosphonylated products in good yields.
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