期刊
SYNTHESIS-STUTTGART
卷 44, 期 4, 页码 489-503出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0031-1290158
关键词
alkylation; enantioselective reaction; nucleophile; organocatalyst; propargylic alcohol; propargylic substitution reaction
资金
- Ministry of Education, Culture, Sports, Science, and Technology of Japan
- Funding Program for Next Generation World-Leading Researchers [GR025]
Recent advances in the transition-metal-catalyzed enantioselective propargylic substitution reactions of propargylic alcohol derivatives with nucleophiles are reviewed in this article. After the disclosure of the first example of a ruthenium-catalyzed propargylic alkylation, various types of enantioselective propargylic substitution reactions, including enantioselective propargylation of aromatic compounds, have been reported in the last eight years. In addition, a variety of enantioselective propargylic alkylations use two distinct catalysts, where the two catalysts work cooperatively to promote the asymmetric reactions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据