期刊
SYNTHESIS-STUTTGART
卷 44, 期 15, 页码 2333-2339出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0031-1290764
关键词
nickel; multicomponent coupling; alkyne; dimethylzinc; vinyl epoxide; cyclopropane
资金
- MEXT, Japan [21350055]
- Grants-in-Aid for Scientific Research [21350055] Funding Source: KAKEN
Nickel catalyzes the multicomponent coupling reaction of vinyl epoxides, alkynes, and dimethylzinc to provide hepta-2,5-dienyl alcohols as a mixture of E- and Z-isomers in high yields. Vinylcyclopropane participates in a similar multicomponent coupling reaction to afford dimethyl alpha-(hepta-2,5-dienyl)malonates with excellent E-stereoselectivity.
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