期刊
SYNTHESIS-STUTTGART
卷 44, 期 8, 页码 1190-1198出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0031-1290591
关键词
diamination; hypervalent iodine; oxidation; catalysis; piperidine
资金
- NSF [NSF CHE 0847258]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0847258] Funding Source: National Science Foundation
A general method for the direct intramolecular diamination of terminal olefins is presented. The reaction, mediated by hypervalent iodine oxidants, produces substituted 3-aminopiperidine scaffolds with high regio- and stereoselectivity, rendering this process relevant to both medicinal chemistry and natural products synthesis.
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