期刊
SYNTHESIS-STUTTGART
卷 -, 期 20, 页码 3209-3219出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1260212
关键词
pyridine; C-H functionalization; alkylation; alkenylation; arylation; acylation; transition-metal catalysis
The direct functionalization of pyridine and related azine derivatives through carbon-carbon bond-forming reactions is reviewed. Various transformations that use a variety of transitionmetal catalysts are covered, including alkylation, alkenylation, arylation, and acylation. In addition to the conventionally observed C2-selectivity for these transformations, recent developments involve selective introduction of newly formed carbon-carbon bonds to the C3- and C4-positions of pyridine and azine nuclei. The reaction scope and a proposed mechanism for each transformation are briefly summarized.
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