期刊
SYNTHESIS-STUTTGART
卷 -, 期 10, 页码 1515-1525出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1260006
关键词
radical reaction; rearrangement; ketones; carboxylic acids; azo compounds
资金
- Deutsche Forschungsgemeinschaft (DFG)
- FAU Erlangen-Nurnberg
The reductive ring-opening of hydroperoxides derived from cyclic ketones leads to alkyl radicals which can effectively be trapped by arenediazonium salts. This synthetic transformation yielding azo carboxylic acids or lactams, after a reductive step, can be classified as a radical version of the well-known Beckmann rearrangement. In this article, we present results on the scope, the limitations and possible applications of this new reaction type.
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