期刊
SYNTHESIS-STUTTGART
卷 -, 期 13, 页码 2245-2253出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0029-1220010
关键词
arylations; C-H activation; dehydrogenation; ruthenium; triazoles
资金
- DFG
- Alexander von Humboldt foundation
The chemoselectivity of ruthenium-catalyzed C-H bond arylations on triazol-4-yl-substituted arenes was found to depend on the substitution pattern of both substrates. While various aryl chlorides led to products stemming from direct arylations, ortho-substituted aryl halides in combination with ortho-alkylated arenes preferentially resulted in oxidative homo-couplings.
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