期刊
SYNTHESIS-STUTTGART
卷 -, 期 4, 页码 517-538出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1258328
关键词
catalysis; asymmetric synthesis; oxidation; hypervalent iodine; C-C bond formation
资金
- Swedish Research Council
- Wenner Foundation
- Gren Foundation
- Carl Trygger Foundation
- Royal Swedish Academy of Sciences
- K & A Wallenberg Foundation
alpha-Functionalized carbonyl compounds are versatile intermediates in organic synthesis. A broad range of both carbon and heteroatom substituents can be introduced into the alpha-position of carbonyl compounds using hypervalent iodine reagents. Herein we summarize the use of these environmentally benign reagents with particular emphasis on catalytic and asymmetric methodology developed over the past decade.
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