期刊
SYNTHESIS-STUTTGART
卷 -, 期 16, 页码 2543-2546出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2008-1067190
关键词
deoxygenation; sulfoxide; sulfide; chemoselective; triflic anhydride
资金
- Razi University Research Council
It was found that the combination of triflic anhydride/potassium iodide was an effective promoter for the deoxygenation of sulfoxides and gave the corresponding Sulfides in excellent yield in acetonitrile at room temperature. It is worth mentioning that this reagent system is chemoselective and tolerates various functional groups, such as alkene, ketone, ester, aldehyde, acid, and oxime.
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