期刊
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
卷 42, 期 2, 页码 231-237出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/15533174.2011.609851
关键词
crystal structure; magnetic property; Mn(II) complex; 1D zigzag chain
资金
- National Natural Science Foundation of China [20771094, 20671083]
- Foundation of Henan Educational Committee [2011B150001]
- Foundation of Henan University of Urban construction [2010JYB007]
A new one-dimensional Mn(II) complex, {[Mn-2(HL)(2)(H2O)(4)]center dot 2DMF}(n) (H3L = 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid), has been prepared and characterized by elemental analyses, IR, TG analysis and single crystal X-ray diffraction. The singlecrystal XRD study revealed that the complex crystallizes in a space group P-1 and has a 1D Zigzag chain. In addition, the variable temperature magnetic susceptibility of complex 1 was measured and weak antiferromagnetic exchange interactions between the neighboring Mn(II) ions was found.
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