期刊
SYNLETT
卷 29, 期 19, 页码 2523-2528出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1610275
关键词
hyperbranched polymer; multicomponent polymerization; alkynes; poly(phosphorus amidine)s; luminescence
资金
- National Science Foundation of China [21774034, 21490573, 21490574, 21788102]
- Natural Science Foundation of Guangdong Province [2016A030306045, 2016A030312002]
- Innovation and Technology Commission of Hong Kong [ITC-CNERC14SC01]
The construction of functional hyperbranched polymers with unique topological structures and distinct properties remains a great challenge. Multicomponent polymerization, as a fascinating polymer synthetic approach, has proved to be a powerful tool for the synthesis of polymers with diverse structures and multifunctionalities, which is a great advantage for the preparation of hyperbranched polymers. In this work, a multicomponent polymerization of alkynes, sulfonyl azide, and iminophosphorane is utilized for the construction of heteroatom-rich hyperbranched poly(phosphorus amidine)s with different topological structures and fluorescence response toward platinum group metal ions.
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