期刊
SYNLETT
卷 25, 期 8, 页码 1116-1120出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1340989
关键词
natural products; drug discovery; prenylation; regioselectivity
资金
- University of Aveiro
- Fundacao para a Ciencia e a Tecnologia (FCT, Portugal)
- European Union
- QREN
- FEDER
- COMPETE [PEst-C/QUI/UI0062/2013]
- FCT
- QOPNA [SFRH/BI/33956/2009]
Strategies towards the synthesis of the natural product platachromoneB and related compounds have been investigated starting from commercially available phloroacetophenone. Direct C-prenylation of (E)-2-styryl-4H-chromen-4-ones was also studied. Methods for the synthesis of new (E)-5,7-dimethoxy-8-(3-methylbut-2-en-1-yl)-2-styryl-4H-chromen-4-ones and (E)-5-hydroxy-7-methoxy-6-(3-methylbut-2-en-1-yl)-2-styryl-4H-chromen-4-ones have also been established and are described for the first time.
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