期刊
SYNLETT
卷 25, 期 7, 页码 1014-1018出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1340872
关键词
natural products; total synthesis; macrolactonization; configuration determination; stereoselectivity
资金
- NSFC [21062006, 21072007, 21272011]
- Hong Kong Research Grants Council [PolyU 5040/10P, PolyU 5037/11P, PolyU 5020/12P, PolyU5030/13P]
- Fong Shu Fook Tong Foundation
- Joyce M. Kuok Foundation
- Shenzhen Bureau of Science, Technology and Information [JC200903160367A, JC201005260220A, JC201005260102A, ZYC201105170351A]
A stereocontrolled total synthesis of the cyclodepsipeptide, itralamide B, has been achieved. Both R- and S-stereoisomers of the side chain were attached to the macrocyclic ring, however, the synthesized structure appears to be different from that of the marine natural product.
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