期刊
SYNLETT
卷 25, 期 17, 页码 2390-2414出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0034-1379210
关键词
alkylation; arylation; alkenylation; introduction of carbonyl groups; halogenation; polycyclic aromatic hydrocarbons
资金
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
- Grants-in-Aid for Scientific Research [25105746] Funding Source: KAKEN
Transition-metal-catalyzed functionalization of unreactive carbon bonds such as C-H, C-O, C-N, and C-F bonds has been extensively studied over the last two decades. In this account we describe our studies on chelation-assisted catalytic transformations of unreactive carbon bonds in aromatic and olefinic compounds. Various C-C bond forming reactions are achieved by catalytic addition of C-H bonds to alkenes and alkynes, and via coupling reactions such as those of C-H, C-O, C-N, and C-F bonds with boronic esters. Methods for the conversion of C-H bonds into C-Si and C-X (X = halogen) bonds are also developed. The C-C bond forming reactions are applied to short syntheses of polycyclic aromatic hydrocarbons.
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