期刊
SYNLETT
卷 24, 期 19, 页码 2465-2471出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1339875
关键词
P-chiral phosphorus ligands; asymmetric catalysis; hydrogenation; cross-coupling
资金
- 'Thousand Plan' Youth program
- Innovation Fund of State Key Laboratory of Bioorganic and Natural Products Chemistry
- Boehringer Ingelheim
- [NSFC-21272254]
- [STCSM-13PJ1410900]
The synthesis of P-chiral phosphorus ligands with novel structures is important for the development of efficient asymmetric catalytic transformations. Here, we describe the development of P-chiral phosphorus ligands such as BIBOP, WingPhos, BI-DIME, and 8 in our laboratory. Conformational rigidity, high tunability of electronic and steric properties, and convenient physical properties are the main features of our ligand design. Progress in developing practical asymmetric hydrogenation and asymmetric cross-coupling reactions are discussed.
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