期刊
SYNLETT
卷 24, 期 3, 页码 327-332出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1317920
关键词
antitumor agents; chromium; cyclization; nickel; stereoselective synthesis
Multikilogram manufacturing process of the Halaven (R) C14-C35 fragment is described. The synthesis features convergent assembly of subunits by iterative asymmetric Ni/Cr-mediated coupling executed in fixed equipment.
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