期刊
SYNLETT
卷 24, 期 3, 页码 363-368出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1318130
关键词
epoxides; stereoselective synthesis; palladium catalysis; acid catalysis; diene synthesis
资金
- University of York
- Elsevier
- Society of Chemical Industry
Mild and efficient routes to (E,E)-and (E,Z)-4-methoxypentadienoic acid esters from readily accessible gamma,delta-epoxydienoates are described. The crucial epoxide methanolysis can be carried out in stereocomplementary ways by the use of either acid-mediated or palladium-catalysed procedures, the latter procedure proving preferable in most cases.
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