期刊
SYNLETT
卷 24, 期 3, 页码 379-382出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1317791
关键词
epoxides; (-)-galanthamine; Heck reaction; metathesis; total synthesis
资金
- Basic Science Research Program through the National Research Foundation of Korea (NRF)
- Ministry of Education, Science and Technology [2011-0007015]
- National Research Foundation of Korea [2011-0007015] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Asymmetric total synthesis of (-)-galanthamine was accomplished starting from an epoxide. Intramolecular Heck reaction of a conjugated diene system was employed to construct the key quaternary carbon center. The cyclohexene-1,3-diol unit of (-)-galanthamine is derived from an optically active epoxy alkenol.
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