期刊
SYNLETT
卷 24, 期 12, 页码 1541-1544出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1339190
关键词
alkynes; rhodium; carbenes; azirines; ring-opening reaction
资金
- MEXT, Japan [22350087]
- Grants-in-Aid for Scientific Research [25102523, 22350087] Funding Source: KAKEN
A rhodium(II)-catalyzed reaction of carbonyl-ene-yne compounds, which are used as furylcarbene precursors, with 2H-azirines gave 1-furyl-2-aza-1,3-dienes as products. We propose that the title compounds are formed by the addition of furylcarbene-rhodium(II) complexes to 2H-azirines followed by opening of 2H-azirine rings.
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