期刊
SYNLETT
卷 24, 期 15, 页码 1910-1914出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0033-1339473
关键词
amino acids; cross-coupling; catalysis; palladium; self-assembly
资金
- MEXT [22550099, 24108719]
- CREST [11103784, 11102545]
- PRESTO from the JST [07051361]
- 'Funding Program for Next generation World-Leading Researchers'
- CSTP
- JURC at ICR, Kyoto University
- Grants-in-Aid for Scientific Research [24108719, 22550099] Funding Source: KAKEN
A PCP pincer palladium-complex-bound norvaline, Boc-l-[Pd]Nva-OMe, was synthesized and fully characterized by NMR, FT-ICR-MS, and X-ray crystallography. Selective N- and C-terminus transformations of Boc-l-[Pd]Nva-OMe were performed by conventional deprotection-condensation procedures to afford lipophilic palladium-bound norvaline derivatives without metal detachment. The N-/C-bisfunctionalized palladium-bound norvaline showed self-assembly properties, as evidenced by supramolecular gel formation. The catalytic activity of the supramolecular gel was assessed in the 1,4-conjugate addition of phenylboronic acid.
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