4.4 Article

Triflic Acid Mediated Fries Rearrangement of 3-Dienyl-2-azetidinones: Facile Synthesis of 3-(But-2-enylidene)quinolin-4(3H)-ones

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SYNLETT
卷 24, 期 7, 页码 865-867

出版社

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1318487

关键词

3-dienyl-beta-lactam; triflic acid; Fries rearrangement; quinolin-4(3H)-one; beta-lactam synthon protocol

资金

  1. CSIR New Delhi [01(2407)/10/EMR-II]

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beta-Lactam-synthon-interceded synthesis of 3-(but-2-enylidene)quinolin-4(3H)-ones has been described via triflic acid mediated Fries rearrangement of 3-butadienyl-2-azetidinones. The described protocol provides a direct access to C-3 functionalized quinolin-4(3H)-ones and does not suffer from the disadvantages associated with conventional routes.

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