期刊
SYNLETT
卷 -, 期 16, 页码 2311-2327出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1317082
关键词
cycloaddition; total synthesis; natural products; tandem reaction; ring opening
In this account we have systematically described the acid-promoted intramolecular cycloadditions of activated cyclopropanes, which were conceptually classified into intramolecular cross-cycloadditions (IMCC) and intramolecular parallel-cycloadditions. The IMCC provided a general and efficient strategy for construction of structurally complex and diverse bridged bicyclic skeletons. The potential of this strategy has been demonstrated by the synthesis of natural products.
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