期刊
SYNLETT
卷 -, 期 17, 页码 2567-2571出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0032-1317179
关键词
conjugate hydrocyanation; 1,4-addition; aromatic enone; green chemistry; nucleophilic addition; potassium hexacyanoferrate(II)
资金
- National Natural Science Foundation of China [21162024]
- Provincial Natural Science Foundation of Gansu [1107RJZA189]
A selective conjugate hydrocyanation of aromatic enones by a one-pot, two-step procedure using potassium hexacyanoferrate(II) as an original eco-friendly cyanide source, potassium hydroxide as a base, and benzoyl chloride as a promoter was described. This protocol has the advantages of a nontoxic cyanide source, high yield, and simple workup procedure.
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