期刊
SYNLETT
卷 -, 期 3, 页码 397-400出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0031-1290204
关键词
versipelostatin A; natural products; spiro compounds; Claisen rearrangement
资金
- Japanese Ministry of Education, Culture, Sports, Science and Technology [23780121]
- Grants-in-Aid for Scientific Research [23780121] Funding Source: KAKEN
The synthesis of the spirotetronate unit of versipelostatin A, a down-regulator of molecular chaperone GRP78, was achieved in ten steps starting from pulegone, via the Johnson-Claisen rearrangement. A model study of the coupling reaction with the octalin unit was also performed.
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