期刊
SYNLETT
卷 -, 期 9, 页码 1331-1334出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0031-1290690
关键词
radical reaction; carbonylation; carbamoylacetates; palladium; photo reaction
资金
- JSPS
- MEXT Japan
- Grants-in-Aid for Scientific Research [23350045, 21106003] Funding Source: KAKEN
We developed a novel synthetic method of carbamoylacetates from alpha-iodoacetate, carbon monoxide, and amines under photoirradiation conditions in the presence of a Pd catalyst. This reaction likely proceeds via interplay of radical and organopalladium species.
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