期刊
SYNLETT
卷 -, 期 12, 页码 1713-1716出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1260930
关键词
copper-catalyzed; trifluoromethylation; decarboxylative; silver oxide; cross-coupling
资金
- National Natural Science Foundation of China [20876021, 20923006]
- Education Department of Liaoning Province [2009S021]
A practical and ligand-free Cu-catalyzed decarboxylative trifluoromethylation of aryl iodides with sodium trifluoroacetate using Ag2O as a promoter was reported. A variety of trifluoromethyl-substituted aromatics are synthesized in moderate to excellent yields and with wide functional-group tolerance under relatively mild reaction conditions.
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