期刊
SYNLETT
卷 -, 期 9, 页码 1255-1258出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0030-1260545
关键词
asymmetric catalysis; enantioselectivity; Friedel-Crafts reaction; organocatalysis; substitution
资金
- JSPS [20245021]
- Grants-in-Aid for Scientific Research [20245021] Funding Source: KAKEN
Whether metal-free chiral phosphoric acid or chiral metal phosphate functions as an active catalyst was confirmed in three reactions. In the aza-Friedel-Crafts and aza-ene-type reactions, a metal-free chiral phosphoric acid, namely, a chiral Bronsted acid, was verified to be the active catalyst. In contrast, the substitution reaction of a-diazoacetate with aldimine was accelerated by a salt-containing chiral phosphoric acid and hence chiral metal phosphate presumably functioned as an active catalyst.
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